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I would try: remove the cause. ditch the collar! Switch to nylon or cotton for going out only- remove when you get home. Wash collar often. Use a preparatory whitener to remove stain gradually over time. Sold in most pet stores. And start grooming more frequently.
 

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Would seem that his collar is causing the stain. Use a different collar & just let the stained fur grow & fall out.
 
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